Stimuli-responsive materials have attracted great interest in catalysis, sensing, and drug delivery applications and are typically constituted by soft components. We present a one-pot synthetic method for a type of inorganic silica-based shape change material that is responsive to water vapor exposure. After the wetting treatment, the cross-sectional shape of aminated mesoporous silica nanoparticles (MSNs) with hexagonal pore lattice changed from hexagonal to six-angle-star, accompanied by the loss of periodic mesostructural order.

We report measurements of the in-plane magnetoelastic coupling in both as-deposited and annealed ultrathin Ta/CoFeB/MgO layers as a function of uniaxial strain, conducted using a four-point bending apparatus. While as-deposited samples show only a weak dependence of the magnetoelastic coupling on the CoFeB layer thickness in the ultrathin regime (<2nm), we observe the onset of a strong thickness dependence upon annealing. This dependence can be modeled as arising from a combination of effective surface and volume contributions to the magnetoelastic coupling.

Helicases are a diverse group of molecular motors that utilize energy derived from the hydrolysis of nucleoside triphosphates (NTPs) to unwind and translocate along nucleic acids. These enzymes play critical roles in nearly all aspects of nucleic acid metabolism, and consequently, a detailed understanding of helicase mechanisms at the molecular level is essential.

Superconductors with periodically ordered mesoporous structures are expected to have properties very different from those of their bulk counterparts. Systematic studies of such phenomena to date are sparse, however, because of a lack of versatile synthetic approaches to such materials. We demonstrate the formation of three-dimensionally continuous gyroidal mesoporous niobium nitride (NbN) superconductors from chiral ABC triblock terpolymer selfassembly- directed sol-gel-derived niobium oxide with subsequent thermal processing in air and ammonia gas.

Hybrid pixel array detectors (HPADs) have a major impact on the science performed at x-ray synchrotron radiation sources. Broadly speaking, HPADs are of either the photon-counting or integrating variety. The success of photoncounting HPADs at storage rings is well described in the contribution by Brönnimann and Trüb.

We provide a pedagogical introduction to the two main variants of real-space quantum Monte Carlo methods for electronic structure calculations: variational Monte Carlo (VMC) and diffusion Monte Carlo (DMC). Assuming no prior knowledge on the subject, we review in depth the Metropolis-Hastings algorithm used in VMC for sampling the square of an approximate wave function, discussing details important for applications to electronic systems.

Electrochemical generation of oxygen via the oxygen evolution reaction (OER) is a key enabling step for many air-breathing electrochemical energy storage devices. IrO2 (Ir4+: 5d5) ranks among the most active known OER catalysts. However, it is unclear how the environment of the Ir4+ oxygen-coordination octahedra affects the OER electrocatalysis. Herein, we present the OER kinetics on a single-crystal, epitaxial SrIrO3(100)p perovskite oxide synthesized using molecular-beam epitaxy on a DyScO3(110) substrate.

X-ray free-electron lasers (XFELs) have inspired the development of serial femtosecond crystallography (SFX) as a method to solve the structure of proteins. SFX datasets are collected from a sequence of protein microcrystals injected across ultrashort X-ray pulses. The idea behind SFX is that diffraction from the intense, ultrashort X-ray pulses leaves the crystal before the crystal is obliterated by the effects of the X-ray pulse.

The mechanical properties of crystalline materials can be substantially modified under confinement. Such modified macroscopic properties are usually governed by the altered microstructures and internal stress fields. Here, we use a parallel plate geometry to apply a quasi-static squeeze flow crushing a colloidal polycrystal while simultaneously imaging it with confocal microscopy. The confocal images are used to quantify the local structure order and, in conjunction with Stress Assessment from Local Structural Anisotropy (SALSA), determine the stress at the single-particle scale.

We explore the effect of transverse confinement on the stability of a Bose-Einstein condensate loaded in a shaken one-dimensional or two-dimensional square lattice. We calculate the decay rate from two-particle collisions. We predict that if the transverse confinement exceeds a critical value, then, for appropriate shaking frequencies, the condensate is stable against scattering into transverse directions. We explore the confinement dependence of the loss rate, explaining the rich structure in terms of resonances. © 2015 American Physical Society.