Publications
Photothermal self-oscillation and laser cooling of graphene optomechanical systems
By virtue of their low mass and stiffness, atomically thin mechanical resonators are attractive candidates for use in optomechanics. Here, we demonstrate photothermal back-action in a graphene mechanical resonator comprising one end of a Fabry-Perot cavity. As a demonstration of the utility of this effect, we show that a continuous wave laser can be used to cool a graphene vibrational mode or to power a graphene-based tunable frequency oscillator.
Spatial distribution of radiation damage to crystalline proteins at 25-300 K
The spatial distribution of radiation damage (assayed by increases in atomic B factors) to thaumatin and urease crystals at temperatures ranging from 25 to 300 K is reported. The nature of the damage changes dramatically at approximately 180 K. Above this temperature the role of solvent diffusion is apparent in thaumatin crystals, as solvent-exposed turns and loops are especially sensitive. In urease, a flap covering the active site is the most sensitive part of the molecule and nearby loops show enhanced sensitivity.
Structural susceptibility and separation of time scales in the van der Pol oscillator
We use an extension of the van der Pol oscillator as an example of a system with multiple time scales to study the susceptibility of its trajectory to polynomial perturbations in the dynamics. A striking feature of many nonlinear, multiparameter models is an apparently inherent insensitivity to large-magnitude variations in certain linear combinations of parameters. This phenomenon of "sloppiness" is quantified by calculating the eigenvalues of the Hessian matrix of the least-squares cost function. These typically span many orders of magnitude.
Computational study of the interaction of freely moving particles at intermediate Reynolds numbers
Motivated by our interest in understanding collective behaviour and self-organization resulting from hydrodynamic interactions, we investigate the two-dimensional dynamics of horizontal arrays of settling cylinders at intermediate Reynolds numbers. To simulate these dynamics, we develop a direct numerical simulation based on the immersed interface method. A novel aspect of our method is its ability to efficiently and accurately couple the dynamics of the freely moving objects with the fluid.
Joint density functional theory of the electrode-electrolyte interface: Application to fixed electrode potentials, interfacial capacitances, and potentials of zero charge
This work explores the use of joint density functional theory, an extension of density functional theory for the ab initio description of electronic systems in thermodynamic equilibrium with a liquid environment, to describe electrochemical systems. After reviewing the physics of the underlying fundamental electrochemical concepts, we identify the mapping between commonly measured electrochemical observables and microscopically computable quantities within an, in principle, exact theoretical framework.
Gate-tuned superfluid density at the superconducting LaAlO 3/SrTiO 3 interface
The interface between the insulating oxides LaAlO 3 and SrTiO 3 exhibits a superconducting two-dimensional electron system that can be modulated by a gate voltage. While the conductivity has been probed extensively and gating of the superconducting critical temperature has been demonstrated, the question as to whether, and if so how, the gate tunes the superfluid density and superconducting order parameter needs to be answered. We present local magnetic susceptibility, related to the superfluid density, as a function of temperature, gate voltage, and location.
Control of valley polarization in monolayer MoS2 by optical helicity
Electronic and spintronic devices rely on the fact that free charge carriers in solids carry electric charge and spin. There are, however, other properties of charge carriers that might be exploited in new families of devices. In particular, if there are two or more minima in the conduction band (or maxima in the valence band) in momentum space, and if it is possible to confine charge carriers in one of these valleys, then it should be possible to make a valleytronic device.
High-contrast imaging of graphene via time-domain terahertz spectroscopy
We demonstrate terahertz (THz) imaging and spectroscopy of single-layer graphene deposited on an intrinsic Si substrate using THz time-domain spectroscopy. A singlecycle THz pulse undergoes multiple internal reflections within the Si substrate, and the THz absorption by the graphene layer accumulates through the multiple interactions with the graphene/Si interface.We exploit the large absorption of the multiply reflected THz pulses to acquire high-contrast THz images of graphene.
Interpreting torsional oscillator measurements: Effect of shear modulus and supersolidity
The torsional oscillator is the chief instrument for investigating supersolidity in solid 4He. These oscillators can be sensitive to the elastic properties of the solid helium, which show anomalies over the same range of temperature in which the supersolid phenomenon appears. In this report we present a detailed study of the influence of the elastic properties of the solid on the periods of torsional oscillators for the various designs that have been commonly employed in supersolid measurements.
Optical spectroscopy of graphene: From the far infrared to the ultraviolet
The unique electronic structure of graphene leads to several distinctive optical properties. In this brief review, we outline the current understanding of two general aspects of optical response of graphene: optical absorption and light emission. We show that optical absorption in graphene is dominated by intraband transitions at low photon energies (in the far-infrared spectral range) and by interband transitions at higher energies (from mid-infrared to ultraviolet). We discuss how the intraband and interband transitions in graphene can be modified through electrostatic gating.