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Evidence of high-temperature exciton condensation in two-dimensional atomic double layers

Cornell Affiliated Author(s)
Author
Z. Wang
D.A. Rhodes
K. Watanabe
T. Taniguchi
J.C. Hone
J. Shan
K.F. Mak
Abstract

A Bose–Einstein condensate is the ground state of a dilute gas of bosons, such as atoms cooled to temperatures close to absolute zero1. With much smaller mass, excitons (bound electron–hole pairs) are expected to condense at considerably higher temperatures2–7. Two-dimensional van der Waals semiconductors with very strong exciton binding are ideal systems for the study of high-temperature exciton condensation. Here we study electrically generated interlayer excitons in MoSe2–WSe2 atomic double layers with a density of up to 1012 excitons per square centimetre.

Journal
Nature
Date Published
Funding Source
DE-SC0013883
DE-SC0019481
DMR-1420634
JPMJCR15F3
Group (Lab)
Jie Shan Group
Kin Fai Mak Group

Long valley lifetime of dark excitons in single-layer WSe2

Cornell Affiliated Author(s)
Author
Y. Tang
K.F. Mak
J. Shan
Abstract

Single-layer transition metal dichalcogenides provide a promising material system to explore the electron’s valley degree of freedom as a quantum information carrier. The valley degree of freedom can be directly accessed by means of optical excitation. However, rapid valley relaxation of optically excited electron-hole pairs (excitons) through the exchange interaction has been a major roadblock. Theoretically such valley relaxation is suppressed in dark excitons, suggesting a potential route for long valley lifetimes.

Journal
Nature Communications
Date Published
Funding Source
DE-SC0019481
-SC0019481
DESC0013883
Group (Lab)
Jie Shan Group
Kin Fai Mak Group

Evolution of interlayer and intralayer magnetism in three atomically thin chromium trihalides

Cornell Affiliated Author(s)
Author
H.H. Kim
B. Yang
S. Li
S. Jiang
C. Jin
Z. Tao
G. Nichols
F. Sfigakis
S. Zhong
C. Li
S. Tian
D.G. Cory
G.-X. Miao
J. Shan
K.F. Mak
H. Lei
K. Sun
L. Zhao
A.W. Tsen
Abstract

We conduct a comprehensive study of three different magnetic semiconductors, CrI3, CrBr3, and CrCl3, by incorporating both few-layer and bilayer samples in van der Waals tunnel junctions. We find that the interlayer magnetic ordering, exchange gap, magnetic anisotropy, and magnon excitations evolve systematically with changing halogen atom. By fitting to a spin wave theory that accounts for nearest-neighbor exchange interactions, we are able to further determine a simple spin Hamiltonian describing all three systems.

Journal
Proceedings of the National Academy of Sciences of the United States of America
Date Published
Funding Source
1749774
1807810
DMR-1749774
DMR-1807810
N00014-18-1-2368
ER17-13-199
RGPIN-2017-03815
11574394
11774423
11822412
NRF-2017K1A3A1A12073407
RGPIN-04178
2016YFA0300504
Group (Lab)
Jie Shan Group
Kin Fai Mak Group

Spin tunnel field-effect transistors based on two-dimensional van der Waals heterostructures

Cornell Affiliated Author(s)
Author
S. Jiang
L. Li
Z. Wang
J. Shan
K.F. Mak
Abstract

A transistor based on spin rather than charge—a spin transistor—could potentially offer non-volatile data storage and improved performance compared with traditional transistors. Many approaches have been explored to realize spin transistors, but their development remains a considerable challenge. The recent discovery of two-dimensional magnetic insulators such as chromium triiodide (CrI 3 ), which offer electrically switchable magnetic order and an effective spin filtering effect, can provide new operating principles for spin transistors.

Journal
Nature Electronics
Date Published
Funding Source
DMR-1719875
NNCI-1542081
1807810
DMR-1807810
N00014-18-1-2368
FA9550-18-1-0480
Group (Lab)
Jie Shan Group
Kin Fai Mak Group

Nonlinear anomalous Hall effect in few-layer WTe 2

Cornell Affiliated Author(s)
Author
K. Kang
T. Li
E. Sohn
J. Shan
K.F. Mak
Abstract

The Hall effect occurs only in systems with broken time-reversal symmetry, such as materials under an external magnetic field in the ordinary Hall effect and magnetic materials in the anomalous Hall effect (AHE) 1 . Here we show a nonlinear AHE in a non-magnetic material under zero magnetic field, in which the Hall voltage depends quadratically on the longitudinal current 2–6 . We observe the effect in few-layer T d -WTe 2 , a two-dimensional semimetal with broken inversion symmetry and only one mirror line in the crystal plane.

Journal
Nature Materials
Date Published
Funding Source
DMR-1719875
NNCI-1542081
W911NF-17-1-0605
Group (Lab)
Jie Shan Group
Kin Fai Mak Group

Probing many-body interactions in monolayer transition-metal dichalcogenides

Cornell Affiliated Author(s)
Author
D. Van Tuan
B. Scharf
Z. Wang
J. Shan
K.F. Mak
I. Žutić
H. Dery
Abstract

Many-body interactions in monolayer transition-metal dichalcogenides are strongly affected by their unique band structure. We study these interactions by measuring the energy shift of neutral excitons (bound electron-hole pairs) in gated WSe2 and MoSe2. Surprisingly, while the blueshift of the neutral exciton X0 in electron-doped samples can be more than 10 meV, the blueshift in hole-doped samples is nearly absent.

Journal
Physical Review B
Date Published
Funding Source
N000141712793
1410407
1503601
DESC0012635
DESC0013883
Group (Lab)
Jie Shan Group
Kin Fai Mak Group

Opportunities and challenges of interlayer exciton control and manipulation

Cornell Affiliated Author(s)
Author
K.F. Mak
J. Shan
Abstract

Advances in van der Waals heterostructures allow the control of interlayer excitons by electrical and other means, promising exciting opportunities for high-temperature exciton condensation and valley–spin optoelectronics. © 2018, Springer Nature Limited.

Journal
Nature Nanotechnology
Date Published
Funding Source
1807810
DMR-1807810
Group (Lab)
Jie Shan Group
Kin Fai Mak Group

Light–valley interactions in 2D semiconductors

Cornell Affiliated Author(s)
Author
K.F. Mak
D. Xiao
J. Shan
Abstract

The emergence of two-dimensional Dirac materials, particularly transition metal dichalcogenides (TMDs), has reinvigorated interest in valleytronics, which utilizes the electronic valley degree of freedom for information storage and processing. Here, we review the basic valley-dependent properties and their experimental demonstrations in single-layer semiconductor TMDs with an emphasis on the effects of band topology and light–valley interactions.

Journal
Nature Photonics
Date Published
Funding Source
1433496
Group (Lab)
Jie Shan Group
Kin Fai Mak Group

Controlling magnetism in 2D CrI3 by electrostatic doping

Cornell Affiliated Author(s)
Author
S. Jiang
L. Li
Z. Wang
K.F. Mak
J. Shan
Abstract

The atomic thickness of two-dimensional materials provides a unique opportunity to control their electrical 1 and optical 2 properties as well as to drive the electronic phase transitions 3 by electrostatic doping. The discovery of two-dimensional magnetic materials 4-10 has opened up the prospect of the electrical control of magnetism and the realization of new functional devices 11 . A recent experiment based on the linear magneto-electric effect has demonstrated control of the magnetic order in bilayer CrI3 by electric fields 12 .

Journal
Nature Nanotechnology
Date Published
Funding Source
DMR-1410407
DMR-1420451
FA9550-16-1-0249
W911NF-17-1-0605
Group (Lab)
Jie Shan Group
Kin Fai Mak Group

An unusual continuous paramagnetic-limited superconducting phase transition in 2D NbSe2

Cornell Affiliated Author(s)
Author
E. Sohn
X. Xi
W.-Y. He
S. Jiang
Z. Wang
K. Kang
J.-H. Park
H. Berger
L. Forró
K.T. Law
J. Shan
K.F. Mak
Abstract

Time reversal and spatial inversion are two key symmetries for conventional Bardeen-Cooper-Schrieffer (BCS) superconductivity1. Breaking inversion symmetry can lead to mixed-parity Cooper pairing and unconventional superconducting properties1-5. Two-dimensional (2D) NbSe2 has emerged as a new non-centrosymmetric superconductor with the unique out-of-plane or Ising spin-orbit coupling (SOC)6-9. Here we report the observation of an unusual continuous paramagnetic-limited superconductor-normal metal transition in 2D NbSe2.

Journal
Nature Materials
Date Published
Funding Source
DESC0013883
1645901
DMR-1644779
W911NF-17-1-0605
DMR-1410407
DMR-1420451
DMR-1645901
16324216
C6026-16W
HKUST3/CRF/13G
Group (Lab)
Jie Shan Group
Kin Fai Mak Group