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Nonlinear rheology of entangled polymer solutions in narrow gaps probed by confocal microscopy

Cornell Affiliated Author(s)

Author

K.A. Hayes
M.R. Buckley
Itai Cohen
L.A. Archer

Abstract

Two likely causes of Type C Damping in highly entangled polymers are interfacial slip and shear banding. To isolate these mechanisms, we use confocal microscopy and particle image velocimetry to visualize flow in a planar-Couette shear. Polybutadiene (Mw=200K, 1.1 M) solutions with different entanglement densities (8≤Z≤56) are sheared in narrow gaps ∼35μm. Not only does the velocity at the boundaries violate the no-slip condition, but the velocity profiles are linear. This is inconsistent with shear banding. The measured shear rates and stresses are used to characterize interfacial slip. © 2008 American Institute of Physics.

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Conference

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-51149100117&doi=10.1063%2f1.2964703&partnerID=40&md5=1ade438ca8bd9bcdac279b15b1b29bd7

DOI

10.1063/1.2964703

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