Nonlinear rheology of entangled polymer solutions in narrow gaps probed by confocal microscopy
Abstract
Two likely causes of Type C Damping in highly entangled polymers are interfacial slip and shear banding. To isolate these mechanisms, we use confocal microscopy and particle image velocimetry to visualize flow in a planar-Couette shear. Polybutadiene (Mw=200K, 1.1 M) solutions with different entanglement densities (8≤Z≤56) are sheared in narrow gaps ∼35μm. Not only does the velocity at the boundaries violate the no-slip condition, but the velocity profiles are linear. This is inconsistent with shear banding. The measured shear rates and stresses are used to characterize interfacial slip. © 2008 American Institute of Physics.
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-51149100117&doi=10.1063%2f1.2964703&partnerID=40&md5=1ade438ca8bd9bcdac279b15b1b29bd7
DOI
10.1063/1.2964703