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High resolution shear profile measurements in entangled polymers

Cornell Affiliated Author(s)

Author

K.A. Hayes
M.R. Buckley
Itai Cohen
L.A. Archer

Abstract

We use confocal microscopy and particle image velocimetry to visualize motion of 250-300 nm. fluorescent tracer particles in entangled polymers subject to a rectilinear shear flow. Our results show linear velocity profiles in polymer solutions spanning a wide range of molecular weights and number of entanglements (8≤Z≤56), but reveal large differences between the imposed and measured shear rates. These findings disagree with recent reports that shear banding is a characteristic flow response of entangled polymers, and instead point to interfacial slip as an important source of strain loss. © 2008 The American Physical Society.

Date Published

Journal

Physical Review Letters

Volume

101

Issue

21

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-56849092586&doi=10.1103%2fPhysRevLett.101.218301&partnerID=40&md5=17725f164f1d37d80543c0bbd4e92bfb

DOI

10.1103/PhysRevLett.101.218301

Group (Lab)

Itai Cohen Group

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