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Direct Visualization of Trimerized States in 1T−TaTe2

Cornell Affiliated Author(s)

Author

Ismail Baggari
Nikhil Sivadas
Gregory Stiehl
Jacob Waelder
Daniel Ralph
Craig Fennie
Lena Kourkoutis

Abstract

Transition-metal dichalcogenides containing tellurium anions show remarkable charge-lattice modulated structures and prominent interlayer character. Using cryogenic scanning transmission electron microscopy (STEM), we map the atomic-scale structures of the high temperature (HT) and low temperature (LT) modulated phases in 1T'-TaTe2. At HT, we directly show in-plane metal distortions which form trimerized clusters and staggered, three-layer stacking. In the LT phase at 93 K, we visualize an additional trimerization of Ta sites and subtle distortions of Te sites by extracting structural information from contrast modulations in plan-view STEM data. Coupled with density functional theory calculations and image simulations, this approach opens the door for atomic-scale visualizations of low temperature phase transitions and complex displacements in a variety of layered systems. © 2020 authors. Published by the American Physical Society. Published by the American Physical Society under the terms of the "https://creativecommons.org/licenses/by/4.0/"Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI.

Date Published

Journal

American Physical Society (APS)

Volume

125

Issue

16

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85094982563&doi=10.1103%2fPhysRevLett.125.165302&partnerID=40&md5=e19a014419e7b053bee3af59478d5f0f

DOI

10.1103/PhysRevLett.125.165302

Funding Source

DMR-1539918
DE-SC0017671
NSF-MRI-1429155
1719875
DMR-1719875

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